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並前往https://www.colby.edu/chemistry/PChem/notes/EntropySpontaneity.pdf

Entropy and Spontaneous Processes dw = –Pext dV dq = Cv ...

dq = Cv dT ... T reversible path, P = Pext dqrev = T dS dwmax = – P dV ... δ CP t. D. Kondepudi, I. Prigogine, Modern Thermodynamics, Wiley, Chichester, ...

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