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HW#4 & Key (2011) – Physical Chemistry for Biochemists 1

pVan der Waals equation:P R TVa2 b m V m P VT VR T22 3V b maVmT VR Tm b2 aVm P ... for C P,m – C V,m in terms ofV m , T, and the gas constants R, a, and b.

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